1,4-Benzenedicarboxylic acid, 2,5-bis[(4-methoxyphenyl)amino]- → 2,9-Dimethoxyquinacridone

HRID 2056976

반응식

HRID 2056976 반응식
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([NH:9][C:10]2[CH:18]=[C:17]([C:19](O)=[O:20])[C:16]([NH:22][C:23]3[CH:28]=[CH:27][C:26]([O:29][CH3:30])=[CH:25][CH:24]=3)=[CH:15][C:11]=2[C:12]([OH:14])=O)=[CH:5][CH:4]=1>O>[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]2[NH:9][C:10]3[C:11]([C:12](=[O:14])[C:5]=2[CH:4]=1)=[CH:15][C:16]1[NH:22][C:23]2[CH:28]=[CH:27][C:26]([O:29][CH3:30])=[CH:25][C:24]=2[C:19](=[O:20])[C:17]=1[CH:18]=3

참가 물질

3

반응물 1

HCID 30848371,4-Benzenedicarboxylic acid, 2,5-bis[(4-methoxyphenyl)amino]-

생성물 1

HCID 1004262,9-Dimethoxyquinacridone수율 101.8%

시약·촉매·용매 1

HCID 962Water용매

실험 절차

2,5-Bis{(4-methoxyphenyl)amino}terephthalic acid (1.02 gm; 2.5 mmol) and polyphosphoric acid (10 gm) were heated at 160° C. for 15 minutes under a nitrogen atmosphere. The mixture was allowed to cool and then poured into iced water (200 ml) when a purple solid precipitated out. This was filtered off, washed with water and methanol, then dried under vacuum over phosphorous pentoxide to give 948 mg (100%) of 2,9-dimethoxyquinacridone.

후처리

  1. temperatureto cool
  2. customprecipitated out
  3. filtrationThis was filtered off
  4. washwashed with water and methanol
  5. dry with materialdried under vacuum over phosphorous pentoxide

출처 및 근거

ORD 기록
ord-4bad7f0997dc4d9d9ff45ff925391e2d
출처 데이터셋
uspto-grants-2008_02
특허 번호
US07335771B2

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