Sodium perfluorobutanesulfonate → HCID 178448399, 화합물

HRID 2057147노트

반응식

HRID 2057147 반응식
C(OP([O-])(OCC)=O)C.[C:10]([IH+:14]([C:21]([CH3:24])([CH3:23])[CH3:22])[C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1)([CH3:13])([CH3:12])[CH3:11].[F:25][C:26]([F:41])([S:37]([O-:40])(=[O:39])=[O:38])[C:27]([F:36])([F:35])[C:28]([F:34])([F:33])[C:29]([F:32])([F:31])[F:30].[Na+]>O>[F:41][C:26]([F:25])([S:37]([O-:40])(=[O:39])=[O:38])[C:27]([F:35])([F:36])[C:28]([F:34])([F:33])[C:29]([F:32])([F:31])[F:30].[C:21]([IH+:14]([C:10]([CH3:13])([CH3:12])[CH3:11])[C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1)([CH3:24])([CH3:23])[CH3:22]

참가 물질

4

반응물 2

HCID 23678450Sodium perfluorobutanesulfonateHCID 178448396HCID 178448396, 화합물

생성물 1

HCID 178448399HCID 178448399, 화합물수율 90.7%

시약·촉매·용매 1

HCID 962Water용매

실험 절차

Di-tert-butylphenyliodonium diethylphosphate (546 mg; 1 mmol) and sodium perfluorobutanesulfonate (354 mg; 1.1 mmol) were dissolved in water (10 ml), and the resultant mixture was extracted three times with methylene chloride (10 ml). The solvent was removed through distillation, and precipitated white solid was washed with ether, followed by recrystallization from a mixture of methylene chloride and ether, to thereby precipitate 561 mg of the target compound as white crystals (yield: 81%).

후처리

  1. extractionthe resultant mixture was extracted three times with methylene chloride (10 ml)
  2. customThe solvent was removed through distillation
  3. customprecipitated white solid
  4. washwas washed with ether
  5. customfollowed by recrystallization from a mixture of methylene chloride and ether

출처 및 근거

ORD 기록
ord-e46242a79252426ea6523b29d38e7097
출처 데이터셋
uspto-grants-2008_02
특허 번호
US07335787B2

반응 노트

불러오는 중…