Sodium Carbonate → 4-Hydroxyisophthalic acid

HRID 2057155

반응식

HRID 2057155 반응식
Br[C:2]1[CH:10]=[CH:9][C:5]([C:6]([OH:8])=[O:7])=[CH:4][C:3]=1[C:11]([OH:13])=[O:12].C([O-])([O-])=[O:15].[Na+].[Na+]>>[OH:15][C:2]1[CH:10]=[CH:9][C:5]([C:6]([OH:8])=[O:7])=[CH:4][C:3]=1[C:11]([OH:13])=[O:12]

참가 물질

3

반응물 2

HCID 10340Sodium CarbonateHCID 813614-Bromo-1,3-benzenedicarboxylic acid

생성물 1

HCID 124904-Hydroxyisophthalic acid수율 82%

실험 절차

The same procedure as described in Example 24 was performed but using 2.45 g (10.0 mmol) of 4-bromoisophthalic acid as the substrate and 2.70 g (25.5 mmol) of Na2CO3 instead of Ca(OH)2. A total of 1.49 g (8.2 mmol, 82% yield) of 4-hydroxyisophthalic acid was collected. The purity was determined by 1H NMR to be 88%.

출처 및 근거

ORD 기록
ord-44522d51b97047ea93e84d115d3643eb
출처 데이터셋
uspto-grants-2008_02
특허 번호
US07335791B1

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