Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Safrole → Safrole oxide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Safrole | HCID 5144 | — |
| 반응물 | Perpropionic acid | HCID 65136 | — |
| 용매 | 1,1-Dichloropropane | HCID 6573 | — |
| 생성물 | Safrole oxide | HCID 101123 | — |
반응 단계
48.82 g (0.3 mol) of 5-(2-propenyl)-1,3-benzodioxole were reacted with 45 g (0.1 mol) of a 20% strength solution of perpropionic acid in dichloropropane at 30° C. as described in Example 1. After a reaction time of 6 hours, the peracid conversion was 96%. 5-(Oxiranylmethyl)-1,3-benzodioxole was formed with a selectivity of 68%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04212809 |
| 출처 데이터셋 | uspto-grants-1980_07 |
| ORD ID | ord-0e6bb625f7d6498f99187530cf82f287 |
| 출처 메모 | uspto-grants-1980_07 |