Alachlor → 2-Chloro-N-(chloromethyl)-N-(2,6-diethylphenyl)acetamide

HRID 2059348

반응식

[CH2:1]([C:3]1[CH:16]=[CH:15][CH:14]=[C:13]([CH2:17][CH3:18])[C:4]=1[N:5]([CH2:10]OC)[C:6](=[O:9])[CH2:7][Cl:8])[CH3:2].O=S(Cl)[Cl:21]>>[CH2:1]([C:3]1[CH:16]=[CH:15][CH:14]=[C:13]([CH2:17][CH3:18])[C:4]=1[N:5]([CH2:10][Cl:21])[C:6](=[O:9])[CH2:7][Cl:8])[CH3:2]

참가 물질

반응물 2

HCID 2078Alachlor

HCID 24386Thionyl Chloride

생성물 1

HCID 1620072-Chloro-N-(chloromethyl)-N-(2,6-diethylphenyl)acetamide

실험 절차

Ten (10.0) g of 2',6'-diethyl-N-(methoxymethyl)-2-chloroacetanilide (common name "alachlor") when refluxed with 60 ml of SOCl2 for periods from 12-24 hours gave little evidence of the formation of 2',6'-diethyl-N-(chloromethyl)-2-chloroacetanilide ("CMA"), the desired product.

출처 및 근거

ORD 기록: ord-19a0615fef344c379deca0b363383311
출처 데이터셋: uspto-grants-1982_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04322553

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