Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Water → HCID 21412112, 화합물
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Water | HCID 962 | — |
| 반응물 | Dimethylformamide | HCID 6228 | — |
| 반응물 | 5-(3-iodopropyl)-5H-dibenzo[a,d]cycloheptene | HCID 23328868 | — |
| 반응물 | Phthalimide potassium salt | HCID 24194345 | — |
| 용매 | Chloroform | HCID 6212 | — |
| 생성물 | HCID 21412112 | HCID 21412112 | — |
반응 단계
5-(3-Iodopropyl)-5H-dibenzo[a,d]cycloheptene, 1.8 g. (0.005 mole), is dissolved in 10 ml. of dimethylformamide. The solution is stirred while 930 mg. (0.0051 mole) of potassium phthalimide is added. When the addition is complete, the mixture is heated to 85°-90° C. for 40 minutes, then cooled, diluted with chloroform and poured into water. The chloroform layer is separated and the aqueous layer extracted further with chloroform. Evaporation of the chloroform gives the product as an oily crystalline solid. Several recrystallizations from isopropyl alcohol gave product, m.p. 125.5°-131.5° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04048223 |
| 출처 데이터셋 | uspto-grants-1977_09 |
| ORD ID | ord-3b5ba246c5794fba8c53474ff6c17a16 |
| 출처 메모 | uspto-grants-1977_09 |