Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
m-Chloroperbenzoic acid → Pyridine, 2-[[(2-methylphenyl)methyl]sulfinyl]-, 1-oxide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | m-Chloroperbenzoic acid | HCID 70297 | — |
| 반응물 | 2-(2-methylphenylmethylthio)pyridine N-oxide | HCID 45692352 | — |
| 용매 | Chloroform | HCID 6212 | — |
| 생성물 | Pyridine, 2-[[(2-methylphenyl)methyl]sulfinyl]-, 1-oxide | HCID 501068 | — |
반응 단계
To a vigorously stirred solution of 6.9 gm (0.03 mol) of 2-(2-methylphenylmethylthio)pyridine N-oxide in 50 ml of chloroform maintained at 0° to 10° C. is slowly added a solution of 6 gm (0.03 mol) MCPBA (85%) in 100 ml of chloroform. When addition is complete the temperature is allowed to rise to ambient. After sixteen hours the reaction solution is washed up in the manner described in Example 139.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04050921 |
| 출처 데이터셋 | uspto-grants-1977_09 |
| ORD ID | ord-e8ec416a33d04210a65bab9cac42d512 |
| 출처 메모 | uspto-grants-1977_09 |