m-Chloroperbenzoic acid → Pyridine, 2-[[(2-methylphenyl)methyl]sulfinyl]-, 1-oxide

HRID 2072255

반응식

HRID 2072255 반응식
[CH3:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[CH2:8][S:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][N+:11]=1[O-:16].C1C=C(Cl)C=C(C(OO)=[O:25])C=1>C(Cl)(Cl)Cl>[CH3:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[CH2:8][S:9]([C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][N+:11]=1[O-:16])=[O:25]

참가 물질

4

반응물 2

HCID 70297m-Chloroperbenzoic acidHCID 456923522-(2-methylphenylmethylthio)pyridine N-oxide

생성물 1

HCID 501068Pyridine, 2-[[(2-methylphenyl)methyl]sulfinyl]-, 1-oxide

시약·촉매·용매 1

HCID 6212Chloroform용매2회

실험 절차

To a vigorously stirred solution of 6.9 gm (0.03 mol) of 2-(2-methylphenylmethylthio)pyridine N-oxide in 50 ml of chloroform maintained at 0° to 10° C. is slowly added a solution of 6 gm (0.03 mol) MCPBA (85%) in 100 ml of chloroform. When addition is complete the temperature is allowed to rise to ambient. After sixteen hours the reaction solution is washed up in the manner described in Example 139.

후처리

  1. additionWhen addition
  2. washAfter sixteen hours the reaction solution is washed up in the manner

출처 및 근거

ORD 기록
ord-e8ec416a33d04210a65bab9cac42d512
출처 데이터셋
uspto-grants-1977_09
특허 번호
US04050921

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