Pyridine → 9,10-Anthracenedione, 1,5-bis(octadecylamino)-

HRID 2072278노트

반응식

HRID 2072278 반응식
Cl[C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[C:9](Cl)[CH:10]=[CH:11][CH:12]=3)[C:7](=[O:18])[C:6]=2[CH:5]=[CH:4][CH:3]=1.[CH2:19]([NH2:37])[CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH3:36].[C:38]([O-])(=O)[CH3:39].[Na+].[N:43]1[CH:48]=[CH:47][CH:46]=[CH:45][CH:44]=1>C1C=CC=CC=1.C([O-])(=O)C.[Cu+2].C([O-])(=O)C>[CH2:19]([NH:37][C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[C:9]([NH:43][CH2:48][CH2:47][CH2:46][CH2:45][CH2:44][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH2:15][CH2:14][CH2:38][CH3:39])[CH:10]=[CH:11][CH:12]=3)[C:7](=[O:18])[C:6]=2[CH:5]=[CH:4][CH:3]=1)[CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH3:36]

참가 물질

7

반응물 4

HCID 1049PyridineHCID 67111,5-DichloroanthraquinoneHCID 15793OctadecylamineHCID 517045Sodium Acetate

생성물 1

HCID 30980749,10-Anthracenedione, 1,5-bis(octadecylamino)-

시약·촉매·용매 2

HCID 8895Cupric acetate촉매HCID 241Benzene용매

실험 절차

A reactor was charged with 1.4 g of 1, 5-dichloroanthraquinone, 33.6 g. of stearyl amine, 1.3 g of sodium acetate, 0.3 g of copper acetate and 3.2 g of pyridine and the reaction was effected at 80° C. for 15 hours under stirring. The resulting red solid was dissolved in benzene and insoluble matters were removed, followed by distillation of benzene and recystallization from glacial acetic acid. Thus 1, 5-di-n-octadecylaminoanthraquinone was obtained by the reaction of the following formula: ##STR7## Preparation of Liquid Developer:

후처리

  1. custominsoluble matters were removed
  2. distillationfollowed by distillation of benzene and recystallization from glacial acetic acid

출처 및 근거

ORD 기록
ord-a0feefa5c5314e0fa83208be9fb5c82c
출처 데이터셋
uspto-grants-1977_09
특허 번호
US04051052

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