Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Pyridine → 1-Amino-2,4-di-n-dodecylaminoanthraquinone
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Pyridine | HCID 1049 | — |
| 반응물 | 1-Amino-2,4-dibromoanthraquinone | HCID 6681 | — |
| 반응물 | Dodecylamine | HCID 13583 | — |
| 반응물 | Potassium Acetate | HCID 517044 | — |
| 촉매 | Cupric acetate | HCID 8895 | — |
| 용매 | Benzene | HCID 241 | — |
| 생성물 | 1-Amino-2,4-di-n-dodecylaminoanthraquinone | HCID 21407063 | — |
반응 단계
A reactor was charged with 19 g of 1-amino-2,4-dibromoanthraquinone, 28 g of dodecylamine, 0.4 g of copper acetate, 5 g of potassium acetate and 40 g of pyridine and the reaction was effected at an elevated temperature of 115°-120° C. for 20 hours under stirring. The reaction product was dissolved in benzene and insoluble matters were separated, followed by distillation of benzene and recrystallization from glacial acetic acid. A blue solid of 1-amino-2,4-di-n-dodecylaminoanthraquinone was obtained by the reaction of the following formula: ##STR8##
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04051052 |
| 출처 데이터셋 | uspto-grants-1977_09 |
| ORD ID | ord-475519ffedd541a484de268e39aa79e6 |
| 출처 메모 | uspto-grants-1977_09 |