Benzenesulfenyl chloride, 2,4-dinitro- → Sulfide, bis(2,4-dinitrophenyl)

HRID 2083438

반응식

HRID 2083438 반응식
[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1[S:13]Cl)([O-:3])=[O:2]>C(O)(=O)C>[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1[S:13][C:5]1[CH:6]=[CH:7][C:8]([N+:10]([O-:12])=[O:11])=[CH:9][C:4]=1[N+:1]([O-:3])=[O:2])([O-:3])=[O:2]

참가 물질

3

반응물 1

HCID 68251Benzenesulfenyl chloride, 2,4-dinitro-

생성물 1

HCID 95960Sulfide, bis(2,4-dinitrophenyl)

시약·촉매·용매 1

HCID 176Acetic Acid용매

실험 절차

To 1.38 g. of 3-butenyltributyltin was added 0.936 g. of 2,4-dinitrobenzene sulfenyl chloride in 20 ml. glacial acetic acid at steam bath temperature. The reaction mixture was warned on the steam bath for 20 minutes, poured into ice water and filtered. The mixture was extracted with pentane, dried and recrystallized from ethanol to yield cyclopropylcarbinyl 2,4-dinitrophenyl sulfide; m.p. 80°-81° C. Analysis for C and H confirmed the composition of the reaction product.

후처리

  1. filtrationfiltered
  2. extractionThe mixture was extracted with pentane
  3. customdried
  4. customrecrystallized from ethanol

출처 및 근거

ORD 기록
ord-9efef575b0d8482798757dad9e38f081
출처 데이터셋
uspto-grants-1978_04
특허 번호
US04085273

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