Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Trifluoroacetic acid → 1-Bromo-2-heptyl-benzene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Trifluoroacetic acid | HCID 6422 | — |
| 반응물 | Triethylsilane | HCID 12052 | — |
| 반응물 | 1-(2-Bromo-phenyl)-heptan-1-ol | HCID 22731273 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | 1-Bromo-2-heptyl-benzene | HCID 22731318 | — |
반응 단계
Following General Procedure J and using 1-(2-Bromo-phenyl)-heptan-1-ol (1.86 g, 6.9 mmol), anhydrous dichloromethane (5 mL), trifluoroacetic acid (2.5 mL, 32.5 mmol) and triethyl silane (5 mL, 31 mmol) followed by flash column chromatography, the title compound was obtained (0.4 g, 23%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06720423B2 |
| 출처 데이터셋 | uspto-grants-2004_04 |
| ORD ID | ord-2704e5e660b648e283de9f673fb2f4a1 |
| 출처 메모 | uspto-grants-2004_04 |