Methyl Bromide → HCID 86587173, 화합물

HRID 2087098노트

반응식

HRID 2087098 반응식
[CH3:1][N:2]([C:4]([CH2:7][C:8]([CH3:11])([CH3:10])[CH3:9])([CH3:6])[CH3:5])[CH3:3].[CH3:12][Br:13]>ClCCl>[Br-:13].[CH3:3][N+:2]([C:4]([CH2:7][C:8]([CH3:11])([CH3:10])[CH3:9])([CH3:5])[CH3:6])([CH3:12])[CH3:1]

참가 물질

4

반응물 2

HCID 6323Methyl BromideHCID 221336n,n,2,4,4-pentamethylpentan-2-amine

생성물 1

HCID 86587173HCID 86587173, 화합물

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

The procedure given in the previous example was followed. Starting with a solution of N,N-dimethyl t-octylamine (5 g, 31.8 mmol) in dichloromethane (5 mL) and methyl bromide (2.0 M solution in t-butyl methyl ether, 42.8 mL, 85.6 mmol), product was obtained as a white solid (7.2 g (90%)). 1H NMR (CDCl3): δ3.35 (s, 9H, —N+(CH3)3), 1.79 (s, 2H, —CH2—), 1.60 (bt, 6H, —C(CH3)2—), 1.11 (s, 9H, —C(CH3)3) ppm.

후처리

  1. customproduct was obtained as a white solid (7.2 g (90%))

출처 및 근거

ORD 기록
ord-a2072f1fdde44317a5964b660b5931a6
출처 데이터셋
uspto-grants-2004_04
특허 번호
US06727387B2

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