5-Octanoyl-2,2-dimethyl-1,3-dioxane-4,6-dione → Decanoic acid, 3-oxo-, ethyl ester

반응식

[C:1]([CH:10]1C(=O)O[C:13](C)([CH3:17])[O:12][C:11]1=[O:19])(=[O:9])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]>C(O)C>[O:9]=[C:1]([CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8])[CH2:10][C:11]([O:12][CH2:13][CH3:17])=[O:19]

참가 물질

실험 절차

The resulting 5-octanoyl-2,2-dimethyl-1,3-dioxane-4,6-dione was allowed to reflux in ethanol for 2 hours, and then concentrated under reduced pressure. The resulting residue was purified using silica gel chromatography (developing solvent: n-hexane/ethyl acetate=8/2) to obtain ethyl 3-oxodecanoate shown by the formula below.

후처리

concentrationconcentrated under reduced pressure
customThe resulting residue was purified

출처 및 근거

ORD 기록: ord-bdc9956995c44e2fb99da03739adaad8
출처 데이터셋: uspto-grants-2013_05
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08436210B2

반응 노트

불러오는 중…

참가 물질

반응물 1

HCID 3567035-Octanoyl-2,2-dimethyl-1,3-dioxane-4,6-dione

생성물 1

HCID 83224Decanoic acid, 3-oxo-, ethyl ester수율 90%

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

후처리

concentrationconcentrated under reduced pressure
customThe resulting residue was purified

출처 및 근거

ORD 기록: ord-bdc9956995c44e2fb99da03739adaad8
출처 데이터셋: uspto-grants-2013_05
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08436210B2

반응 노트

불러오는 중…