Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Water → Oxirane, 2-((4-chlorophenyl)methyl)-
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Water | HCID 962 | — |
| 반응물 | m-Chloroperbenzoic acid | HCID 70297 | — |
| 반응물 | 1-Allyl-4-chlorobenzene | HCID 11019064 | — |
| 용매 | Chloroform | HCID 6212 | — |
| 생성물 | Oxirane, 2-((4-chlorophenyl)methyl)- | HCID 148012 | — |
반응 단계
To a solution of 3-(4-chlorophenyl)prop-1-ene (9.0 g) in chloroform (100 ml) was added portionwise metachloroperbenzoic acid (12.2 g), and the solution was stirred for 5 h at room temperature. The mixture was poured into water, the water layer was separated and the organic layer washed successively with sodium bicaronate, sodium sulphite and water. After drying, evaporation of the solvent gave 1-(4-chlorophenyl)-2,3-epoxypropane as a pale yellow oil. (9.51 g). NMR in CDCl3 :
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04933357 |
| 출처 데이터셋 | uspto-grants-1990_06 |
| ORD ID | ord-b212209cb977459caa6ffe79f2a61af2 |
| 출처 메모 | uspto-grants-1990_06 |