HCID 54323543, 화합물 → 19915-11-8

HRID 2107802노트

반응식

HRID 2107802 반응식
[CH3:1][CH2:2][C:3](=[O:9])[CH2:4][CH2:5][CH:6]=[CH:7][CH3:8]>C(OCC)(=O)C.[Pd]>[C@@H:5]12[CH2:6][CH2:7][CH2:8][C@@H:1]1[CH2:2][C:3](=[O:9])[CH2:4]2

참가 물질

4

반응물 1

HCID 54323543HCID 54323543, 화합물

생성물 1

HCID 1265497619915-11-8수율 104.7%

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 8857Ethyl Acetate용매

실험 절차

A solution of the cis-bicyclo[3.3..0]oct-6-ene-3-one (6.2 g 0.05 mol) in 150 mL of ethyl acetate containing 0.50 g of 10% Pd/C was hydrogenated at 25 psi for 11/2 hours. The catalyst was removed by filtering through Celite and the solvent evaporated to give 6.5 g of cis-bicyclo[3.3.0]-octane-3-one (100%). TLC (SiO2, CH2Cl2) Rf =0.35 (I2, brown).

후처리

  1. custom2 hours
  2. customThe catalyst was removed
  3. filtrationby filtering through Celite
  4. customthe solvent evaporated

출처 및 근거

ORD 기록
ord-c0c0b15441734bc287ba5bd2ab883027
출처 데이터셋
uspto-grants-1990_06
특허 번호
US04935509

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