2-Trans,6-trans,10-trans-geranylgeranyl diphosphate(3-) → syn-Copalyl diphosphate

HRID 2113253노트

반응식

[O:1]([CH2:10]/[CH:11]=[C:12](/[CH2:14][CH2:15]/[CH:16]=[C:17](\[CH3:29])/[CH2:18][CH2:19]/[CH:20]=[C:21](/[CH2:23][CH2:24][CH:25]=[C:26]([CH3:28])[CH3:27])\[CH3:22])\[CH3:13])[P:2]([O:5][P:6]([O-:9])([O-:8])=[O:7])(=[O:4])[O-:3].C/C(/CC[C@H]1[C@@]2(C)CCCC(C)(C)[C@H]2CCC1=C)=C\CO>>[CH3:13]/[C:12](/[CH2:14][CH2:15][C@H:16]1[C@@:21]2([CH3:22])[CH2:23][CH2:24][CH2:25][C:26]([CH3:28])([CH3:27])[C@@H:20]2[CH2:19][CH2:18][C:17]1=[CH2:29])=[CH:11]\[CH2:10][O:1][P:2]([O:5][P:6]([OH:9])([OH:8])=[O:7])([OH:3])=[O:4]

참가 물질

반응물 2

HCID 54971052-Trans,6-trans,10-trans-geranylgeranyl diphosphate(3-)

HCID 91697686Copalol

생성물 1

HCID 5281991syn-Copalyl diphosphate

실험 절차

Chemicals. The preparation of (E,E,E)-geranylgeranyl diphosphate (GGPP), and ent- and syn-copalyl diphosphate (CPP), from the corresponding copalol stereoisomers (Yee and Coates 1992), has been previously described (Mohan et al. 1996). Unless otherwise noted, all other chemicals were purchased from Fisher Scientific (Fairlawn, N.J., USA).

출처 및 근거

ORD 기록: ord-fc9042de1aa84f42b61ce73e68ff26cf
출처 데이터셋: uspto-grants-2009_04
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07525016B1

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