Lithium bis((trifluoromethyl)sulfonyl)azanide → HCID 178483696, 화합물

HRID 2116843

반응식

HRID 2116843 반응식
[N-:1]([S:9]([C:12]([F:15])([F:14])[F:13])(=[O:11])=[O:10])[S:2]([C:5]([F:8])([F:7])[F:6])(=[O:4])=[O:3].[Li+].[CH3:17][N:18]([C:20]([N:23]([CH3:25])[CH3:24])(Cl)[Cl:21])[CH3:19]>O>[N-:1]([S:2]([C:5]([F:8])([F:6])[F:7])(=[O:4])=[O:3])[S:9]([C:12]([F:15])([F:14])[F:13])(=[O:11])=[O:10].[CH3:17][N:18]([C+:20]([N:23]([CH3:25])[CH3:24])[Cl:21])[CH3:19]

참가 물질

4

반응물 2

HCID 3816071Lithium bis((trifluoromethyl)sulfonyl)azanideHCID 125447451,1-Dichloro-N,N,N',N'-tetramethylmethanediamine

생성물 1

HCID 178483696HCID 178483696, 화합물수율 85.2%

시약·촉매·용매 1

HCID 962Water용매2회

실험 절차

134.1 g (0.467 mol) of lithium bis(trifluoromethanesulfonyl)imide in 200 ml of water are added with stirring at room temperature to a solution of 80.0 g (0.468 mol) of bis(dimethylamino)dichloromethane in 300 ml of water. The mixture is stirred for half an hour, and the solid is subsequently filtered off. After repeated washing with 100 ml of water, the crystals formed are dried at 50° C. under a reduced pressure of 10.0 Pa, giving 165.5 g of bis(dimethylamino)chlorocarbenium bis(trifluoromethanesulfonyl)imide, corresponding to a yield of 85.1%.

후처리

  1. filtrationthe solid is subsequently filtered off
  2. washAfter repeated washing with 100 ml of water
  3. customthe crystals formed
  4. customare dried at 50° C. under a reduced pressure of 10.0 Pa

출처 및 근거

ORD 기록
ord-61f7532d13544a869923ec3cb9b1a9db
출처 데이터셋
uspto-grants-2008_10
특허 번호
US07439395B2

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