Lithium dimethylamide → 1,3-Dimethyl-2-dimethylaminoimidazolidinium nitrate
반응식
[N+:1]([O-:4])([O-:3])=[O:2].[CH3:5][NH+:6]1[CH2:10][CH2:9][N:8]([CH3:11])[CH:7]1Cl.[CH3:13][N-:14][CH3:15].[Li+]>C(#N)C>[N+:1]([O-:4])([O-:3])=[O:2].[CH3:5][NH+:6]1[CH2:10][CH2:9][N:8]([CH3:11])[CH:7]1[N:14]([CH3:15])[CH3:13]참가 물질
4
실험 절차
3.00 g (15.34 mmol) of 1,3-dimethyl-2-chloroimidazolidinium nitrate and 0.78 g (15.29 mmol) of lithium dimethylamide are dissolved in 20 ml of acetonitrile under a protective-gas atmosphere (argon). The reaction mixture is stirred for 5 hours at room temperature, and LiCl is subsequently filtered off. The salt LiCl is washed with 5 ml of acetonitrile, and the organic phases are combined. The solvent is distilled off, and the residue is dried under reduced pressure at 7 Pa and 50° C., giving 2.91 g of 1,3-dimethyl-2-dimethylaminoimidazolidinium nitrate as a liquid, corresponding to a yield of 92.2%.