Methanol → 2-ethyl-2-adamantyl Methacrylate p-acetoxystyrene

HRID 2120031노트

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HRID 2120031 반응식
[C:1]([O:6][C:7]1([CH2:17][CH3:18])[CH:14]2[CH2:15][CH:10]3[CH2:11][CH:12]([CH2:16][CH:8]1[CH2:9]3)[CH2:13]2)(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:19]([O:22][C:23]1[CH:30]=[CH:29][C:26]([CH:27]=[CH2:28])=[CH:25][CH:24]=1)(=[O:21])[CH3:20].N(C(C)(C)C(OC)=O)=NC(C)(C)C(OC)=O.CO>C(O)(C)C.CC(C)=O>[C:1]([O:6][C:7]1([CH2:17][CH3:18])[CH:8]2[CH2:16][CH:12]3[CH2:11][CH:10]([CH2:15][CH:14]1[CH2:13]3)[CH2:9]2)(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:19]([O:22][C:23]1[CH:30]=[CH:29][C:26]([CH:27]=[CH2:28])=[CH:25][CH:24]=1)(=[O:21])[CH3:20]

참가 물질

7

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HCID 887MethanolHCID 757631,1'-Dimethyl 2,2'-(1,2-diazenediyl)bis(2-methylpropanoate)HCID 758214-Ethenylphenyl acetateHCID 98136452-Ethyl-2-methacryloyloxyadamantane

생성물 1

HCID 865871472-ethyl-2-adamantyl Methacrylate p-acetoxystyrene

시약·촉매·용매 2

HCID 180Acetone용매HCID 3776Isopropanol용매2회

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온도
75 °C

실험 절차

Into a flask were charged 39.7 g (0.16 mol) of 2-ethyl-2-adamantyl methacrylate, 103.8 g (0.64 mol) of p-acetoxystyrene and 265 g of isopropanol, and the mixture was heated up to 75° C. under a nitrogen atmosphere. Into this solution was dropped a solution prepared by dissolving 11.05 g (0.048 mol) of dimethyl 2,2′-azobis(2-methylpropionate) in 22.11 g of isopropanol. The mixture was aged for about 0.3 hours at 75° C., and for about 12 hours under reflux, then, diluted with acetone. The reaction solution was poured into a large amount of methanol to precipitate a polymer which was filtrated. The amount of the resulted copolymer of 2-ethyl-2-admantyl methacrylate and p-acetoxystyrene was 250 g (weight of wet cake containing methanol).

후처리

  1. additionInto this solution was dropped a solution
  2. customprepared
  3. temperaturefor about 12 hours under reflux
  4. customto precipitate a polymer which
  5. filtrationwas filtrated
  6. addition250 g (weight of wet cake containing methanol)

출처 및 근거

ORD 기록
ord-b566d380804248c1b39787bf7b7a0245
출처 데이터셋
uspto-grants-2004_02
특허 번호
US06689531B2

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