Nickel Acetate → HCID 178435672, 화합물

HRID 21497

반응식

HRID 21497 반응식
C([O-])(=O)C.[Ni+2:5].C([O-])(=O)C.[CH2:10]([C:12]1[C:32]2[N:33]=[C:14]([CH:15]=[C:16]3[NH:43][C:19](=[CH:20][C:21]4[C:22]([CH2:41][CH3:42])=[C:23]([CH2:39][CH3:40])[C:24]([N:38]=4)=[CH:25][C:26]4[NH:30][C:29]([CH:31]=2)=[C:28]([CH2:34][CH3:35])[C:27]=4[CH2:36][CH3:37])[C:18]([CH2:44][CH3:45])=[C:17]3[CH2:46][CH3:47])[C:13]=1[CH2:48][CH3:49])[CH3:11]>>[Ni:5].[CH2:39]([C:23]1[C:24]2[N:38]=[C:21]([CH:20]=[C:19]3[NH:43][C:16](=[CH:15][C:14]4[C:13]([CH2:48][CH3:49])=[C:12]([CH2:10][CH3:11])[C:32]([N:33]=4)=[CH:31][C:29]4[NH:30][C:26]([CH:25]=2)=[C:27]([CH2:36][CH3:37])[C:28]=4[CH2:34][CH3:35])[C:17]([CH2:46][CH3:47])=[C:18]3[CH2:44][CH3:45])[C:22]=1[CH2:41][CH3:42])[CH3:40]

참가 물질

3

반응물 2

HCID 9756Nickel AcetateHCID 135742508Octaethyl-porphyrin

생성물 1

HCID 178435672HCID 178435672, 화합물

실험 절차

The nickel acetate is added to the octaethylporphyrin solution; the mixture which results is refluxed for about 24 hours until the electronic spectrum of the reaction mixture indicates that chelation is complete. The reaction mixture is then concentrated to 7 mL and allowed to cool to room temperature of about 22°. Product which precipitates is recovered by filtration, dissolved in a mixed solvent composed of 5 mL dichloromethane and 2 mL methanol, and recrystallized, yielding Ni octaethylporphyrin.

후처리

  1. customthe mixture which results
  2. temperatureis refluxed for about 24 hours until the electronic spectrum of the reaction mixture
  3. concentrationThe reaction mixture is then concentrated to 7 mL
  4. customProduct which precipitates
  5. filtrationis recovered by filtration
  6. dissolutiondissolved in a mixed solvent
  7. customrecrystallized

출처 및 근거

ORD 기록
ord-813b69f14299474f9736d8b2058a4e23
출처 데이터셋
uspto-grants-1995_06
특허 번호
US05424305

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