Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Water → N'-t-butyl-N-(2-hydroxymethylbenzoyl)hydrazine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Water | HCID 962 | — |
| 반응물 | Phthalide | HCID 6885 | — |
| 반응물 | Sodium Hydroxide | HCID 14798 | — |
| 반응물 | tert-Butylhydrazine | HCID 81890 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | N'-t-butyl-N-(2-hydroxymethylbenzoyl)hydrazine | HCID 19368051 | 13.5% |
반응 단계
t-Butylhydrazine (0.1 mol) in 75 ml ethanol was treated with 50% aqueous sodium hydroxide (0.11 mol). Phthalide (0.1 mol) was added and the mixture was refluxed for 5 days. After cooling, water was added and the crude product was isolated by filtration. Filtration through silica gel afforded N'-t-butyl-N-(2-hydroxymethylbenzoyl)hydrazine (3.0 g): m.p. 116°-118° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05424333 |
| 출처 데이터셋 | uspto-grants-1995_06 |
| ORD ID | ord-70f1a15021854145b1b9c22f57f6e88f |
| 출처 메모 | uspto-grants-1995_06 |