Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Benzoyl chloride → 1,2-Dibenzoyl-1-(tert-butyl)hydrazine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Benzoyl chloride | HCID 7412 | — |
| 반응물 | Tert-butylhydrazine ethanedioate(1:1) | HCID 269219 | — |
| 용매 | Toluene | HCID 1140 | — |
| 용매 | Hexane | HCID 8058 | — |
| 용매 | Sodium Hydroxide | HCID 14798 | — |
| 생성물 | 1,2-Dibenzoyl-1-(tert-butyl)hydrazine | HCID 86307 | 15% |
반응 단계
The 1,1-dimethylethylhydrazine oxalate (2 g) was dissolved in toluene and neutralized with 50% aqueous sodium hydroxide. To this solution was added benzoyl chloride (4.02 g) and sodium hydroxide (50% Aq. solution) (2.45 g) at 25° C. The reaction mixture was warmed to room temperature and stirred 3 hours. The mixture was diluted with hexane and filtered to afford the product as a white solid (0.5 g).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05424333 |
| 출처 데이터셋 | uspto-grants-1995_06 |
| ORD ID | ord-086b219308224dd4b83325a657c1c1e7 |
| 출처 메모 | uspto-grants-1995_06 |