Acetic Acid → HCID 53866074, 화합물
반응식
[CH3:1][C:2]([CH2:8][CH2:9][CH2:10][CH:11]=[C:12]([CH3:15])[CH2:13][CH3:14])=[CH:3][C:4](OC)=[O:5].[H-].[Al+3].[Li+].[H-].[H-].[H-].C(O)(=O)C>CCOCC>[CH3:1][C:2]([CH2:8][CH2:9][CH2:10][CH:11]=[C:12]([CH3:15])[CH2:13][CH3:14])=[CH:3][CH2:4][OH:5]참가 물질
5
실험 절차
A solution of 2 g. of methyl 3,8-dimethyldeca-2,7-dienoate in 20 ml. of dry ether is added with stirring to 0.4 g. of lithium aluminum hydride covered in ether at 0°. After about one hour, 2.5 ml. of acetic acid is added. The mixture is washed with ice water and the ether phase dried and evaporated to yield 3,8-dimethyldeca-2,7-dien-1-ol which is treated with phosphorus tribromide to yield 1-bromo-3,8-dimethyldeca-2,7-diene.
후처리
- washThe mixture is washed with ice water
- dry with materialthe ether phase dried
- customevaporated
출처 및 근거
- ORD 기록
- ord-98fe19b8a53841539d0c45dfde330990
- 출처 데이터셋
- uspto-grants-1979_01
- 특허 번호
- US04137273
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