4-(Tetradecyloxy)benzoic acid → Phenyl 3'-nitro-4'-tetradecyloxybiphenyl-4-carboxylate

HRID 2166003

반응식

HRID 2166003 반응식
[N+:1]([C:4]1[CH:5]=[C:6]([C:25]2[CH:30]=[CH:29][C:28]([C:31]([OH:33])=[O:32])=[CH:27][CH:26]=2)[CH:7]=[CH:8][C:9]=1[O:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])([O-:3])=[O:2].C(O[C:49]1[CH:57]=[CH:56][C:52](C(O)=O)=[CH:51][CH:50]=1)CCCCCCCCCCCCC.OC1C=CC(C(OC[C@@H](C)CC)=O)=CC=1.ClC1C=C(O)C=CC=1C(OC[C@@H](C)CC)=O>>[N+:1]([C:4]1[CH:5]=[C:6]([C:25]2[CH:30]=[CH:29][C:28]([C:31]([O:33][C:49]3[CH:57]=[CH:56][CH:52]=[CH:51][CH:50]=3)=[O:32])=[CH:27][CH:26]=2)[CH:7]=[CH:8][C:9]=1[O:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])([O-:3])=[O:2]

참가 물질

5

반응물 4

HCID 2894104-(Tetradecyloxy)benzoic acidHCID 13530950Benzoic acid, 4-hydroxy-, (2S)-2-methylbutyl esterHCID 14533552(S)-2-methylbutyl 2-chloro-4-hydroxybenzoateHCID 200435223'-Nitro-4'-tetradecyloxybiphenyl-4-carboxylic acid

생성물 1

HCID 86743015Phenyl 3'-nitro-4'-tetradecyloxybiphenyl-4-carboxylate

실험 절차

The procedure of Example 1 was followed except using 3'-nitro-4'-tetradecyloxybiphenyl-4-carboxylic acid instead of said 4-tetradecyloxybenzoic acid and (S)-2-methylbutyl 4-hydroxybenzoate instead of said (S)-2-methylbutyl 2-chloro-4-hydroxybenzoate. There resulted (S)-2-methylbutyloxycarbonyl]phenyl 3'-nitro-4'-tetradecyloxybiphenyl-4-carboxylate].

출처 및 근거

ORD 기록
ord-4a1538fe537c4805b228ab07725754df
출처 데이터셋
uspto-grants-1990_07
특허 번호
US04943386

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