Ethanol → HCID 20498860, 화합물

HRID 2166733노트

반응식

HRID 2166733 반응식
[CH2:1]([OH:7])/[CH:2]=[CH:3]/[CH:4]=[CH:5]/[CH3:6].[Li].[CH3:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14].C(O)C>C1COCC1>[CH2:1]([O:7][CH2:9]/[CH:10]=[CH:11]/[CH:12]=[CH:13]/[CH3:14])/[CH:2]=[CH:3]/[CH:4]=[CH:5]/[CH3:6]

참가 물질

6

반응물 4

HCID 702EthanolHCID 8058HexaneHCID 641256trans,trans-2,4-Hexadien-1-olHCID 3028194Lithium

생성물 1

HCID 20498860HCID 20498860, 화합물

시약·촉매·용매 1

HCID 8028Tetrahydrofuran용매

실험 절차

A mixture of 10 g of the polymer from Example 17, 2.2 ml of sorbyl alcohol (2,4-hexadienol) and 0.1 g of lithium metal in 100 ml of THF was refluxed under nitrogen for 18 hours. The mixture was then cooled and a 10-ml portion was poured into 100 ml of hexane containing 2 ml of ethanol to obtain the solid product. To further purify, it was redissolved in 10 ml of THF and suction filtered through a fine frit into 100 ml of water. The precipitated solid was collected and dried.

후처리

  1. temperaturewas refluxed under nitrogen for 18 hours
  2. temperatureThe mixture was then cooled
  3. customto obtain the solid product
  4. customTo further purify
  5. dissolutionit was redissolved in 10 ml of THF
  6. filtrationsuction filtered through a fine frit into 100 ml of water
  7. customThe precipitated solid was collected
  8. customdried

출처 및 근거

ORD 기록
ord-40c19d5a3dd04f2c8d0a64cf7f14986d
출처 데이터셋
uspto-grants-1983_06
특허 번호
US04388448

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