Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Hydrogen Peroxide → 1,2-Epoxycyclooctane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Hydrogen Peroxide | HCID 784 | — |
| 반응물 | Chloroform | HCID 6212 | — |
| 반응물 | 1-Cyclooctene | HCID 13609 | — |
| 반응물 | 2-Propanone, 1,1,1,3-tetrachloro- | HCID 28188 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | 1,2-Epoxycyclooctane | HCID 67513 | 83% |
반응 단계
There were added 13.68 parts of a 50% aqueous hydrogen peroxide to a refluxing mixture of 3.92 parts of tetrachloroacetone, 11.58 parts of cyclooctene and 149 parts of chloroform. Water was removed continuously as it was formed, over a period of 4 hours of heating. The removed water was then added to the reaction mixture. The organic phase was then separated from the aqueous phase. Based on VPC analysis is there was obtained an 83% yield of cyclooctene oxide.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04389529 |
| 출처 데이터셋 | uspto-grants-1983_06 |
| ORD ID | ord-4325ce9dd96c484c9bfa7f553a421349 |
| 출처 메모 | uspto-grants-1983_06 |