Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Toluene → N'-t-butyl-N-pyrenonecarbonyl-N'-(3-toluoyl)hydrazine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Toluene | HCID 1140 | — |
| 반응물 | Diethyl Ether | HCID 3283 | — |
| 반응물 | Hexane | HCID 8058 | — |
| 반응물 | tert-Butylhydrazine monohydrochloride | HCID 81889 | — |
| 반응물 | Pyrenonecarbonyl chloride | HCID 131717420 | — |
| 용매 | Hydroxide | HCID 961 | — |
| 생성물 | N'-t-butyl-N-pyrenonecarbonyl-N'-(3-toluoyl)hydrazine | HCID 131717419 | — |
반응 단계
To a stirred suspension of t-butyl hydrazine hydrochloride (0.02 mol) in toluene (20 ml) and aqueous hydroxide (5 ml of 50% solution) at room temperature was added pyrenonecarbonyl chloride (0.01 mol). After stirring the reaction mixture for 20 minutes, ether and hexane were added and the solid product was filtered and washed with water. The solid product (0.5 g) was stirred in toluene (10 ml) and aqueous sodium hydroxide and m-toluoyl chloride (0.8 g) was added dropwise. After stirring for 5 hours, hexane and ether were added and the solid product filtered and air dried.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05424333 |
| 출처 데이터셋 | uspto-grants-1995_06 |
| ORD ID | ord-4ace12a6e29447b3bbd6b021605bd28a |
| 출처 메모 | uspto-grants-1995_06 |