Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Hydracrylonitrile → Bis(2-cyanoethyl) phosphorochloridite
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Hydracrylonitrile | HCID 8011 | — |
| 반응물 | Tetrahydrofuran | HCID 8028 | — |
| 반응물 | Triethylamine | HCID 8471 | — |
| 반응물 | Phosphorus trichloride | HCID 24387 | — |
| 생성물 | Bis(2-cyanoethyl) phosphorochloridite | HCID 11390133 | — |
반응 단계
In the second reaction vessel 3-hydroxypropionitrile (20 mmol) and triethylamine (2.8 mL, 20 mmol) were added to a solution of phosphorus trichloride (10 mmol) in THF (25 mL) under dry nitrogen. The mixture was stirred for 10 min at room temperature to give bis(2-cyanoethyl) phosphorochloridite (28).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08193384B2 |
| 출처 데이터셋 | uspto-grants-2012_06 |
| ORD ID | ord-07a034ec63f6492a84428633fd197f33 |
| 출처 메모 | uspto-grants-2012_06 |