참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Sodium Acetate | HCID 517045 | — |
| 반응물 | Trivinyl(3-chloropropyl)silane | HCID 23630656 | — |
| 용매 | Dimethylformamide | HCID 6228 | — |
| 생성물 | 3-Acetoxypropyltrivinylsilane | HCID 57945596 | 76% |
반응 단계
As shown in Reaction Scheme 24, 3-chloropropyltrivinylsilane (1.0 g, 5.35 mmol) and sodium acetate (0.87 g, 10.7 mmol) were dissolved in 17 mL of dimethylformamide (DMF), and the reaction mixture was heated at 120° C. for 12 hours. After the reaction, the organic layer was separated after addition of distilled water and ether. The organic layer was dried over MgSO4, concentrated by evaporation of solvent, and the resulting residue was purified by column chromatography (n-Hex: EA=10:1, Rf=0.4) to give 855 mg (76% yield) of pure 3-acetoxypropyltrivinylsilane.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US08197903B2 |
|---|
| 출처 데이터셋 | uspto-grants-2012_06 |
|---|
| ORD ID | ord-672dfd5c3911452085a6ee1da2c6cf62 |
|---|
| 출처 메모 | uspto-grants-2012_06 |
|---|
