Thiophenol → Methyl 3-bromo-6-(phenylthiomethyl)-2-methoxybenzoate

HRID 2177747노트

반응식

HRID 2177747 반응식
BrC1C(OC)=C(C=CC=1C[S:14][C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][C:16]=1C)C(OCC)=O.[Br:24][C:25]1[C:26]([O:37][CH3:38])=[C:27]([C:32]([CH2:35]Br)=[CH:33][CH:34]=1)[C:28]([O:30][CH3:31])=[O:29].C1(S)C=CC=CC=1>>[Br:24][C:25]1[C:26]([O:37][CH3:38])=[C:27]([C:32]([CH2:35][S:14][C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)=[CH:33][CH:34]=1)[C:28]([O:30][CH3:31])=[O:29]

참가 물질

4

반응물 3

HCID 7969ThiophenolHCID 66685947Methyl 3-bromo-6-bromomethyl-2-methoxybenzoate2회HCID 67107587Ethyl 3-bromo-2-methoxy-(2-methylphenylthiomethyl)benzoate

생성물 1

HCID 67107558Methyl 3-bromo-6-(phenylthiomethyl)-2-methoxybenzoate

실험 절차

Prepared by proceeding in a similar manner to Intermediate 77, starting from methyl 3-bromo-6-bromomethyl-2-methoxybenzoate (Intermediate 89) and thiophenol and used without further characterization.

후처리

  1. customPrepared

출처 및 근거

ORD 기록
ord-92a985f3592b48198eb145b67b2426b7
출처 데이터셋
uspto-grants-2015_06
특허 번호
US09067905B2

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