3-Methoxybenzenethiol → Methyl 3-bromo-2-methoxy-6-(3-methoxyphenylthiomethyl)benzoate

반응식

[Br:1][C:2]1[C:3]([O:21][CH3:22])=[C:4]([C:10]([CH2:13][S:14][C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)=[CH:11][CH:12]=1)[C:5]([O:7][CH2:8]C)=[O:6].BrC1C(OC)=C(C(CBr)=CC=1)[C:27](OC)=[O:28].COC1C=C(S)C=CC=1>>[Br:1][C:2]1[C:3]([O:21][CH3:22])=[C:4]([C:10]([CH2:13][S:14][C:15]2[CH:20]=[CH:19][CH:18]=[C:17]([O:28][CH3:27])[CH:16]=2)=[CH:11][CH:12]=1)[C:5]([O:7][CH3:8])=[O:6]

참가 물질

반응물 3

HCID 849893-Methoxybenzenethiol

HCID 66685947Methyl 3-bromo-6-bromomethyl-2-methoxybenzoate2회

HCID 67107500HCID 67107500, 화합물

생성물 1

HCID 67107527Methyl 3-bromo-2-methoxy-6-(3-methoxyphenylthiomethyl)benzoate

실험 절차

Prepared by proceeding in a similar manner to Intermediate 73, starting from methyl 3-bromo-6-bromomethyl-2-methoxybenzoate (Intermediate 89) and 3-methoxythiophenol.

후처리

customPrepared

출처 및 근거

ORD 기록: ord-adee3e3ab5554938a23d44f5cfdd2ce7
출처 데이터셋: uspto-grants-2015_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US09067905B2

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