Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Water → HCID 86758101, 화합물
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Water | HCID 962 | — |
| 반응물 | Isopropanol | HCID 3776 | — |
| 반응물 | tert-Butyl bromoacetate | HCID 79177 | — |
| 반응물 | Syn-benzaldehyde oxime | HCID 5324470 | — |
| 반응물 | Sodium | HCID 5360545 | — |
| 생성물 | HCID 86758101 | HCID 86758101 | — |
반응 단계
Z-Benzaldoxime (5.64 g, 46.61 mmol) and t-butyl bromoacetate (7.58 mL, 10 g, 51.27 mmol) were added successively to a solution of sodium (1.07 g, 0.047 g-atom) in 2-propanol (120 mL). The suspension was stirred for 2 h and then poured into water (100 mL). Extraction with dichloromethane, followed by drying over anhydrous magnesium sulfate and concentration gave a residue which was chromatographed on silica gel. Elution with 60% ethyl acetate-hexanes gave t-butyl N-benzylideneglycine N-oxide.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06399600B1 |
| 출처 데이터셋 | uspto-grants-2002_06 |
| ORD ID | ord-20dd4b4f9dab4814971fc75f32f5e21f |
| 출처 메모 | uspto-grants-2002_06 |