Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Oxygen → 1,3-Adamantanediol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Oxygen | HCID 977 | — |
| 반응물 | Adamantane | HCID 9238 | — |
| 반응물 | 1-Adamantanol | HCID 64152 | — |
| 반응물 | 1-Hydroxy-6-(trifluoromethyl)benzotriazole | HCID 688194 | — |
| 용매 | Acetic Acid | HCID 176 | — |
| 생성물 | 1,3-Adamantanediol | HCID 573829 | — |
반응 단계
A mixture of 10 mmol of adamantane, 0.8 mmol of 6-trifluoromethyl-1-hydroxybenzotriazole, 0.06 mmol of acetylacetonatocobalt(III), and 25 ml of acetic acid was stirred at 90° C. in an oxygen atmosphere (1 atm) for 8 hours. A gas chromatographic analysis of products in a reaction mixture found that 1-adamantanol and 1,3-adamantanediol were formed in yields of 38% and 4%, respectively, with a conversion rate from adamantane of 48%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06403521B1 |
| 출처 데이터셋 | uspto-grants-2002_06 |
| ORD ID | ord-c57151d71df74416857985f15f37c92a |
| 출처 메모 | uspto-grants-2002_06 |