Oxalyl chloride → HCID 22452672, 화합물

HRID 2185892노트

반응식

HRID 2185892 반응식
[CH3:1][O:2][C:3]1[CH:4]=[C:5]([C:13]([OH:15])=O)[C:6]2[CH2:7][CH2:8][CH2:9][CH2:10][C:11]=2[CH:12]=1.C(Cl)(=O)C([Cl:19])=O>C(Cl)Cl.CN(C=O)C>[CH3:1][O:2][C:3]1[CH:4]=[C:5]([C:13]([Cl:19])=[O:15])[C:6]2[CH2:7][CH2:8][CH2:9][CH2:10][C:11]=2[CH:12]=1

참가 물질

5

반응물 2

HCID 65578Oxalyl chlorideHCID 22452645HCID 22452645, 화합물

생성물 1

HCID 22452672HCID 22452672, 화합물

시약·촉매·용매 2

HCID 6228Dimethylformamide촉매HCID 6344Dichloromethane용매

실험 절차

To a solution of 3-methoxy-5,6,7,8-tetrahydro-1-naphthalenecarboxylic acid (0.20 g, 0.97 mmol) in DCM (5 mL) was added oxalyl chloride (0.11 mL, 1.21 mmol) and 1 drop of DMF. The mixture was stirred at room temperature for 2 h. The solvent was removed in vacuo and 3-methoxy-5,6,7,8-tetrahydro-1-naphthalenecarbonyl chloride was used without purification.

후처리

  1. customThe solvent was removed in vacuo and 3-methoxy-5,6,7,8-tetrahydro-1-naphthalenecarbonyl chloride
  2. customwas used without purification

출처 및 근거

ORD 기록
ord-de0db4e5718c4fb7b41a5a6b641bc610
출처 데이터셋
uspto-grants-2002_06
특허 번호
US06403601B1

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