HCID 86641123, 화합물 → HCID 59289251, 화합물

HRID 2191041노트

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HRID 2191041 반응식
[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S:8]([O:11][C@@H:12]2[C@H:16]3[O:17]C(C)(C)[O:19][CH2:20][C@H:15]3[O:14][C@@H:13]2[O:23][CH3:24])(=[O:10])=[O:9])=[CH:4][CH:3]=1>C(O)(=O)C.O>[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S:8]([O:11][C@@H:12]2[C@@H:16]([OH:17])[C@@H:15]([CH2:20][OH:19])[O:14][C@@H:13]2[O:23][CH3:24])(=[O:10])=[O:9])=[CH:4][CH:3]=1

참가 물질

4

반응물 1

HCID 86641123HCID 86641123, 화합물

생성물 1

HCID 59289251HCID 59289251, 화합물

시약·촉매·용매 2

HCID 176Acetic Acid용매HCID 962Water용매

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온도
50 °C

실험 절차

Compound 35.4 (32.18 g, 89.9 mmol) was dissolved in 400 mL of a 3:1 mixture of acetic acid and water. The mixture was heated to 50° C. for 2 h and the solvent was removed under reduced pressure. The residue was subjected to a column chromatography eluting with EtOAc to give compound 35.5.

후처리

  1. customthe solvent was removed under reduced pressure
  2. washeluting with EtOAc

출처 및 근거

ORD 기록
ord-c5fde4042bc2468d92e457bd8b6fdac7
출처 데이터셋
uspto-grants-2012_12
특허 번호
US08324179B2

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