(-)-Isopulegol → Isopulegol, (+)-

반응식

[CH3:1][C@H:2]1[CH2:7][C@@H:6]([OH:8])[C@H:5]([C:9]([CH3:11])=[CH2:10])[CH2:4][CH2:3]1>O>[CH3:1][C@@H:2]1[CH2:7][C@H:6]([OH:8])[C@@H:5]([C:9]([CH3:11])=[CH2:10])[CH2:4][CH2:3]1

참가 물질

반응 조건

온도: 2.5 °C

실험 절차

The catalyst solution obtained in Example 7-1 was cooled to 0 to 5° C., and 1.54 g (10.0 mmol) of l-citronellal was added dropwise to the solution, followed by stirring at 0 to 5° C. overnight. After completion of the reaction, 2 ml of water was added to the reaction mixture, and an organic layer was analyzed with gas chromatography. As a result, substrate conversion was 89.2%, isopulegol conversion was 88.1%, and the ratio of l-n-isopulegol to the other isomers was 96.9:3.1.

후처리

additionwas added to the reaction mixture

출처 및 근거

ORD 기록: ord-b62a33e3a8ca493084c7e035560aff2d
출처 데이터셋: uspto-grants-2012_12
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08329931B2

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참가 물질

반응물 1

HCID 170833(-)-Isopulegol

생성물 1

HCID 1268090Isopulegol, (+)-

시약·촉매·용매 1

HCID 962Water용매

반응 조건

온도: 2.5 °C

실험 절차

후처리

additionwas added to the reaction mixture

출처 및 근거

ORD 기록: ord-b62a33e3a8ca493084c7e035560aff2d
출처 데이터셋: uspto-grants-2012_12
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08329931B2

반응 노트

불러오는 중…