Vinyl Acetate → 2-Vinyl-2-azabicyclo[2.2.1]hept-5-en-3-one
반응식
[CH:1]12[CH2:7][CH:4]([CH:5]=[CH:6]1)[C:3](=[O:8])[NH:2]2.[C:9](OC=C)(=O)[CH3:10]>[Na+].[Na+].Cl[Pd+2](Cl)(Cl)Cl>[CH:9]([N:2]1[C:3](=[O:8])[CH:4]2[CH2:7][CH:1]1[CH:6]=[CH:5]2)=[CH2:10]참가 물질
4
실험 절차
A solution of 2-azabicyclo[2.2.1]hept-5-en-3-one (0.5 g, 4.6 mmole) in vinyl acetate (3 ml, 33 mmole) with sodium tetrachloropalladate (15 mg, 0.05 mmole) was refluxed for 5 days. The product, Compound 6, was isolated by evaporation of the volatiles. Analysis by Gas Liquid Chromatography-Mass Spectrometry (GLC-MS) was consistent with the predicted molecular weight.
출처 및 근거
- ORD 기록
- ord-3865ab6554404ec9b59a3a1abbb6b7da
- 출처 데이터셋
- uspto-grants-2012_06
- 특허 번호
- US08202833B2
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