Tris(2-cyanoethyl)phosphine → HCID 20520070, 화합물

HRID 2198379노트

반응식

HRID 2198379 반응식
[C:1]([CH2:3][CH2:4][P:5]([CH2:10][CH2:11][C:12]#[N:13])[CH2:6][CH2:7][C:8]#[N:9])#[N:2].[I:14][CH2:15][CH2:16][O:17][CH3:18]>C(#N)C>[I-:14].[C:1]([CH2:3][CH2:4][P+:5]([CH2:10][CH2:11][C:12]#[N:13])([CH2:6][CH2:7][C:8]#[N:9])[CH2:15][CH2:16][O:17][CH3:18])#[N:2]

참가 물질

4

반응물 2

HCID 77639Tris(2-cyanoethyl)phosphineHCID 791361-Iodo-2-methoxyethane

생성물 1

HCID 20520070HCID 20520070, 화합물

시약·촉매·용매 1

HCID 6342Acetonitrile용매

실험 절차

135.2 g (0.7 mole) of tris-(2-cyanoethyl)-phosphine are dissolved, under nitrogen, in 500 ml of boiling acetonitrile and then 130.2 g (0.7 mole) of 1-iodo-2-methoxyethane are added. The mixture is refluxed for 12 hours. After rapid filtration of the hot solution and cooling, the reaction product crystallises out and is collected by suction filtration and dried in vacuo at 60° C.

후처리

  1. temperatureThe mixture is refluxed for 12 hours
  2. filtrationAfter rapid filtration of the hot solution
  3. temperaturecooling
  4. customthe reaction product crystallises out
  5. filtrationis collected by suction filtration
  6. customdried in vacuo at 60° C.

출처 및 근거

ORD 기록
ord-7f8f318d56d141eab7ba343afa67d7a3
출처 데이터셋
uspto-grants-1982_11
특허 번호
US04357280

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