Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Sodium borohydride → 9-Hydroxymethyl-9,10-dihydro-9,10-methanoanthracene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Sodium borohydride | HCID 4311764 | — |
| 반응물 | 9,10-Dihydro-9,10-methanoanthracene-9-carboxaldehyde | HCID 12404141 | — |
| 용매 | Methanol | HCID 887 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | 9-Hydroxymethyl-9,10-dihydro-9,10-methanoanthracene | HCID 13069082 | — |
반응 단계
A solution of 9-formyl-9,10-dihydro-9,10-methanoanthracene (200 mg) and sodium borohydride (60 mg) in methanol (5 ml) was stirred at room temperature for 30 minutes. The reaction mixture was diluted with water and extracted with ethyl acetate. The ethyl acetate layer was washed with water, dried over anhydrous sodium sulfate and evaporated to dryness to give 9-hydroxymethyl-9,10-dihydro-9,10-methanoanthracene. M.P. 165°-166° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04358620 |
| 출처 데이터셋 | uspto-grants-1982_11 |
| ORD ID | ord-b4b5c81661214b2ab17ab7850509a70e |
| 출처 메모 | uspto-grants-1982_11 |