참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Potassium cyanate | HCID 11378442 | — |
| 반응물 | 9-Tosyloxymethyl-9,10-dihydro-9,10-methanoanthracene | HCID 20519959 | — |
| 용매 | Water | HCID 962 | — |
| 용매 | Dimethylformamide | HCID 6228 | — |
| 생성물 | (9,10-Dihydro-9,10-methano-9-anthryl)acetonitrile | HCID 13069087 | — |
반응 단계
A mixture of 9-tosyloxymethyl-9,10-dihydro-9,10-methanoanthracene (188 mg) and potassium cyanate (40 mg) in dimethylformamide (2 ml) was heated at 150° C. for 7 hours. The reaction mixture was diluted with water and extracted with benzene. The benzene extract was washed with water, dried over anhydrous sodium sulfate and evaporated to dryness to give crude crystals of (9,10-dihydro-9,10-methano-9-anthryl)acetonitrile, which was recrystallized from isopropanol to give pure crystals. M.P. 130°-131° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04358620 |
|---|
| 출처 데이터셋 | uspto-grants-1982_11 |
|---|
| ORD ID | ord-94d72a7e56384f7589e3e478ca5d4832 |
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| 출처 메모 | uspto-grants-1982_11 |
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