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Sodium Bicarbonate → 4-[4-(1,1-Dimethylheptyl)-2-hydroxyphenyl]-2-butanol

HRID 2199013
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HRID 2199013 반응식
C([O:8][C:9]1[CH:14]=[C:13]([C:15]([CH3:23])([CH3:22])[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21])[CH:12]=[CH:11][C:10]=1[CH2:24][CH2:25][CH:26]([OH:28])[CH3:27])C1C=CC=CC=1.C(=O)(O)[O-].[Na+].[H][H]>[Pd].C(O)C>[CH3:23][C:15]([C:13]1[CH:12]=[CH:11][C:10]([CH2:24][CH2:25][CH:26]([OH:28])[CH3:27])=[C:9]([OH:8])[CH:14]=1)([CH3:22])[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21]
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참가 물질

6

반응물 3

HCID 516892Sodium BicarbonateHCID 205179964-[2-Benzyloxy-4-(1,1-dimethylheptyl)phenyl]-2-butanolHCID 178418361HCID 178418361, 화합물

생성물 1

HCID 205179974-[4-(1,1-Dimethylheptyl)-2-hydroxyphenyl]-2-butanol

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 702Ethanol
용매

실험 절차

A mixture of 390 mg. (1.02 mmols.) of 4-[2-benzyloxy-4-(1,1-dimethylheptyl)phenyl]-2-butanol, 360 mg. of solid sodium bicarbonate, 100 mg. of 10% palladium-on-carbon and 10 ml. of ethanol was stirred under one atmosphere of hydrogen for 20 minutes. The reaction mixture was filtered through diatomaceous earth with ethyl acetate and evaporated to an oil. The oil was purified via rapid column chromatography on silica gel eluted with ether to give a quantitative yield of the title compound as an oil.

후처리

  1. additionA mixture of 390 mg
  2. filtrationThe reaction mixture was filtered through diatomaceous earth with ethyl acetate
  3. customevaporated to an oil
  4. customThe oil was purified via rapid column chromatography on silica gel
  5. washeluted with ether

출처 및 근거

ORD 기록
ord-f3ef2bc9099a45a9baa80840ee7f1355
출처 데이터셋
uspto-grants-1982_11
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US04360700

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