Acetaldehyde → HCID 71525790, 화합물

HRID 2205249노트

반응식

HRID 2205249 반응식
[CH2:1]=[C:2]([CH:4]1[CH2:8][CH2:7][CH2:6][C:5]1=[O:9])[CH3:3].[CH:10](=[O:12])[CH3:11].B(F)(F)F.CCOCC>ClCCCl>[CH3:3][C:2]1=[CH:4][CH2:8][CH2:7][CH2:6][C:5](=[O:9])[O:12][CH:10]([CH3:11])[CH2:1]1

참가 물질

5

반응물 3

HCID 177AcetaldehydeHCID 8000Boron trifluoride etherateHCID 150247662-(Prop-1-en-2-yl)cyclopentan-1-one

생성물 1

HCID 71525790HCID 71525790, 화합물수율 35.1%

시약·촉매·용매 1

HCID 111,2-Dichloroethane용매

실험 절차

Following the general procedure as described in Example 1, 2-(prop-1-en-2-yl)cyclopentanone (1.24 g, 10 mmol), acetaldehyde (0.53 g, 12 mmol) and boron trifluoride etherate (0.14 g, 1.0 mmol) in 1,2-dichloroethane (10 mL) were reacted to give the title product as a colorless liquid (0.59 g, 35% yield). Single Z-isomer.

후처리

  1. customwere reacted

출처 및 근거

ORD 기록
ord-5d126e99e40145b481c9889e9880cc6e
출처 데이터셋
uspto-grants-2016_06
특허 번호
US09371262B2

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