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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 2206891생성일: 2026년 10월 26일

Sodium Carbonate → Chromium Arabinose Carbonate

https://huagongshe.com/reaction/2206891

반응식

참여 물질

역할이름HCID투입량
반응물Sodium CarbonateHCID 10340—
반응물Sodium HydroxideHCID 14798—
반응물D-ArabinoseHCID 66308—
반응물Chromium(3+) trichloride hexahydrateHCID 166918—
반응물Chromium arabinoseHCID 86664110—
용매EthanolHCID 702—
용매WaterHCID 962—
생성물Chromium Arabinose CarbonateHCID 131735874—

반응 조건

온도90 °C

반응 단계

30 g of arabinose and 7 g of chromium chloride hexahydrate were dissolved in 60 g of water at 75° C. with stirring to produce a solution. The pH of the solution was raised to about 4 by adding an aqueous solution containing 20 wt % of sodium carbonate. The pH of the solution was then further raised to 10 by rapidly in one portion a suitable amount of adding an aqueous solution containing 20 wt % of sodium hydroxide. The temperature was then raised to 90° C. In less than 10 minutes after the temperature reached 90° C., a blue transparent solution having a strong laser scattering characteristic was then obtained. This strong laser scattering property indicated formation of chromium arabinose nanoclusters. Ethanol was then added into the solution to precipitate the nanoclusters. Next, the precipitate was collected by filtration and then dried alone. Atomic absorption spectroscopy of the thus-obtained nanoclusters indicated that the nanoclusters had a chromium cont of 5.85%. Or the alcohol precipitate was mixed with mannitol and co-dried for further formulation use.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US09375449B2
출처 데이터셋uspto-grants-2016_06
ORD IDord-d14b728e1d4a4a6e9200cdeb891e1873
출처 메모uspto-grants-2016_06