1-Chloro-1-chloromethyl-1-silacyclopentane → 1-Chloromethyl-1-(4-chlorophenyl)-1-silacyclopentane

HRID 2209823노트

반응식

HRID 2209823 반응식
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([Mg]Br)=[CH:4][CH:3]=1.Cl[Si:11]1([CH2:16][Cl:17])[CH2:15][CH2:14][CH2:13][CH2:12]1>>[Cl:17][CH2:16][Si:11]1([C:5]2[CH:6]=[CH:7][C:2]([Cl:1])=[CH:3][CH:4]=2)[CH2:15][CH2:14][CH2:13][CH2:12]1

참가 물질

3

반응물 2

HCID 193820151-Chloro-1-chloromethyl-1-silacyclopentaneHCID 178478191HCID 178478191, 화합물

생성물 1

HCID 193820071-Chloromethyl-1-(4-chlorophenyl)-1-silacyclopentane

실험 절차

In the same apparatus and procedures as Example 1 was reacted 83 ml of 4-chlorophenylmagnesiumbromide solution (1.0 M in diethylether) with 1-chloro-1-chloromethyl-1-silacyclopentane prepared from the above procedure i) for 5 hrs. In the same method as Example 1 was treated the reaction product to give 5.20 g of 1-chloromethyl-1-(4-chlorophenyl)-1-silacyclopentane (b.p. 108°-110° C./0.5 mmHg).

후처리

  1. customprepared from the above procedure i) for 5 hrs
  2. additionIn the same method as Example 1 was treated the reaction product

출처 및 근거

ORD 기록
ord-dbcacf7e60af4e438f6e9aabc5f86163
출처 데이터셋
uspto-grants-1995_10
특허 번호
US05455356

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