2,2'-Bithiophene → 5-Bromo-2-chloro-1-(5-(2-thienyl)-2-thienylmethyl)benzene

반응식

[S:1]1[CH:5]=[CH:4][CH:3]=[C:2]1[C:6]1[S:7][CH:8]=[CH:9][CH:10]=1.[Br:11][C:12]1[CH:13]=[CH:14][C:15]([Cl:20])=[C:16]([CH:19]=1)[CH:17]=O>>[Br:11][C:12]1[CH:13]=[CH:14][C:15]([Cl:20])=[C:16]([CH2:17][C:5]2[S:1][C:2]([C:6]3[S:7][CH:8]=[CH:9][CH:10]=3)=[CH:3][CH:4]=2)[CH:19]=1

참가 물질

반응물 2

HCID 681202,2'-Bithiophene

HCID 106089255-Bromo-2-chlorobenzaldehyde

생성물 1

HCID 666080525-Bromo-2-chloro-1-(5-(2-thienyl)-2-thienylmethyl)benzene

실험 절차

2,2′-Bithiophene and 5-bromo-2-chlorobenzaldehyde obtained in Reference Example 16-(1) were used and treated in a manner similar to Reference Example 9 to give the target compound. APCI-Mass m/Z 369/371 (M+H).

후처리

additiontreated in a manner similar to Reference Example 9
customto give the target compound

출처 및 근거

ORD 기록: ord-01f892247f0946ec8d8ba4eba7b53094
출처 데이터셋: uspto-grants-2012_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08202984B2

반응 노트

불러오는 중…