Toluene → HCID 178506761, 화합물

HRID 2213931노트

반응식

HRID 2213931 반응식
[C:1]([NH-:5])([CH3:4])([CH3:3])[CH3:2].[Li+:6].C1COCC1.C1(C)C=CC=CC=1.[CH3:19][C:20]1[C:25]([CH3:26])=[C:24]([CH3:27])[C:22](=[CH2:23])[C:21]=1[CH3:28]>CCCCC>[C:1]([NH:5][CH2:23][C:22]1([Li:6])[C:24]([CH3:27])=[C:25]([CH3:26])[C:20]([CH3:19])=[C:21]1[CH3:28])([CH3:4])([CH3:3])[CH3:2]

참가 물질

6

반응물 4

HCID 1140TolueneHCID 8028TetrahydrofuranHCID 144751TetramethylfulveneHCID 10964401Lithium t-butylamide

생성물 1

HCID 178506761HCID 178506761, 화합물

시약·촉매·용매 1

HCID 8003Pentane용매

실험 절차

200 mg (2.53 mmol) of lithium tert-butylamide are dissolved in 50 ml of pentane and 2 ml of THF and admixed with 2.5 g of a 9:1 mixture of toluene and 2,3,4,5-tetramethylfulvene. The reaction solution is stirred overnight, which results in precipitation of the product. The solvent is removed under reduced pressure, the residue is taken up in pure pentane and collected on a frit. After washing twice with 20 ml each time of pentane, the white, pulverulent product is dried under reduced pressure.

후처리

  1. customwhich results in precipitation of the product
  2. customThe solvent is removed under reduced pressure
  3. customcollected on a frit
  4. washAfter washing twice with 20 ml each time of pentane
  5. customthe white, pulverulent product is dried under reduced pressure

출처 및 근거

ORD 기록
ord-e803fffe37a7469fa2206e010e17d208
출처 데이터셋
uspto-grants-2006_09
특허 번호
US07105690B2

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