[1,2,3]Thiadiazolo[5,4-b]pyridin-6-ylmethanol → [1,2,3]Thiadiazolo[5,4-b]pyridine-6-carbaldehyde

HRID 2214965노트

반응식

HRID 2214965 반응식
[N:1]1[C:9]2[C:4](=[N:5][CH:6]=[C:7]([CH2:10][OH:11])[CH:8]=2)[S:3][N:2]=1>[O-2].[O-2].[Mn+4]>[N:1]1[C:9]2[C:4](=[N:5][CH:6]=[C:7]([CH:10]=[O:11])[CH:8]=2)[S:3][N:2]=1

참가 물질

3

반응물 1

HCID 21873601[1,2,3]Thiadiazolo[5,4-b]pyridin-6-ylmethanol

생성물 1

HCID 11355675[1,2,3]Thiadiazolo[5,4-b]pyridine-6-carbaldehyde수율 51.6%

시약·촉매·용매 1

HCID 178418406HCID 178418406, 화합물촉매

실험 절차

The alcohol (iv) (0.10 g) was oxidised with manganese dioxide to afford a solid (51 mg).

출처 및 근거

ORD 기록
ord-63eb7a7bf0c34c8d80ab82756f7c5027
출처 데이터셋
uspto-grants-2006_09
특허 번호
US07109213B2

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