1-(9-Azabicyclo[4.2.1]non-2-en-2-yl)ethanone → HCID 86748134, 화합물

반응식

[CH3:1][N:2]1[CH:8]2[CH2:9][CH2:10][CH:3]1[CH:4](C(=O)C)[CH2:5][CH2:6][CH2:7]2.[C:14](C1C2NC(CCC=1)CC2)(=[O:16])C.C[N:27]1C2CCC1C(C(=O)C)CC2>>[CH3:14][O:16][N:27]=[C:7]1[CH2:6][CH2:5][CH2:4][CH:10]2[CH2:9][CH:8]1[N:2]([CH3:1])[CH2:3]2

참가 물질

반응물 3

HCID 4317341-(9-Azabicyclo[4.2.1]non-2-en-2-yl)ethanone

HCID 18966537HCID 18966537, 화합물

HCID 18995706HCID 18995706, 화합물

생성물 1

HCID 86748134HCID 86748134, 화합물

실험 절차

Similarly when N-methyl-2-acetyl-9-azabicyclo[4.2.1]nonane, which can be prepared from 2-acetyl-9-azabicyclo[4.2.1]non-2-ene which is commercially available, is substituted for N-methyl-2-acetyl-8-azabicyclo[3.2.1]octane, compound (5), N-methyl-8-azabicyclo[4.2.1]nonan-2-one methyl oxime is obtained.

출처 및 근거

ORD 기록: ord-ce765784ef564d11b07ef45e92d48c28
출처 데이터셋: uspto-grants-1994_09
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05346911

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