Acenaphthene → Acenaphthylene, dodecahydro-

HRID 2231788

반응식

HRID 2231788 반응식
[CH2:1]1[C:11]2=[C:12]3[C:7](=[CH:8][CH:9]=[CH:10]2)[CH:6]=[CH:5][CH:4]=[C:3]3[CH2:2]1>[Rh]>[CH2:1]1[CH:11]2[CH:12]3[CH:7]([CH2:8][CH2:9][CH2:10]2)[CH2:6][CH2:5][CH2:4][CH:3]3[CH2:2]1

참가 물질

3

반응물 1

HCID 6734Acenaphthene

생성물 1

HCID 102215Acenaphthylene, dodecahydro-수율 100%

시약·촉매·용매 1

HCID 23948Rhodium촉매

실험 절차

Acenaphthene was hydrogenated by the same procedure as in Example 4 except that the catalyst was replaced by a 0.5% Rh/Al2O3 catalyst and reaction was effected at 125° C. for 40 minutes. Perhydroacenaphthene was produced in a yield of 100%, containing 3.4% of No. 1 isomer, 4.7% of No. 2 isomer, and 4.1% of No. 3 isomer, indicating a selectivity of No. 4 isomer of 89.7%.

출처 및 근거

ORD 기록
ord-495967a37cb24998b825afdddc0a0e2d
출처 데이터셋
uspto-grants-1988_11
특허 번호
US04783565

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